THE POLYMER SOCIETY OF KOREA

연구논문 초록집

초록 검색

세션명 대학원생 구두발표 (III)
발표장 제11-2회장
논문코드 O11-18
발표일 2024-04-3
발표시간 13:00-13:15
논문제목 Unprecedented high-mobility organic mixed ionic-electronic conductors with unidirectionally-aligned crystalline polymer chains
발표자 조일영
발표자 소속 광주과학기술원
저자 조일영, 윤명한
소속 광주과학기술원
논문초록 Herein, we report high-performance organic electrochemical transistors (OECTs) based on unidirectionally morphology-controlled organic mixed ion-electron conductor (OMIEC) films. To realize the unidirectional polymer chain alignment, we incorporated alkyl-ethylene glycol hybrid side-chains into the OMIEC polymer to ensure the necessary hydrophobicity and pre-aggregation. Furthermore, we fabricated thin films using the wet-transfer method which facilitated the alignment of polymer fibrils under the influence of drag force. Various surface and crystallographic characterizations of the resulting unidirectionally-aligned OMIEC polymer film demonstrated that the polymer fibrils are well-aligned in a direction conducive to charge transport. Finally, this approach enabled the fabrication of an OECT with an unprecedentedly large figure-of-merit exceeding 800 F cm-1 V-1 s-1 and charge mobility over 8 cm2 V-1 s-1.